Synthesis of cobaltaferracarboranes: two methods
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 805-806
- https://doi.org/10.1039/c39730000805
Abstract
The addition of Na+C5H5 – and FeCl2 to (C5H5)-CoIII(C2B7H9) previously reduced with sodium naphthalide formed the heterobimetallocarborane, (C5H5)CoIII(C2B7H9)FeIII(C5H5); a larger homologue of this cobaltaferracarborane, (C5H5)CoIII(C2B9H11)FeIII(C5H5, was prepared by the reaction of C5H5)CoIII(C2B10H12) with ethanolic potassium hydroxide in the presence of FeCl2 and C5H6.Keywords
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