Two methoxycarbonylketen equivalents as dienophiles in the Diels–Alder reaction
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1227-1228
- https://doi.org/10.1039/c39820001227
Abstract
Methyl methoxypropiolate and methyl (phenylthio)propiolate give Diels–Alder adducts with 1,3-dienes; the adducts with cyclopentadienes give methyl 3-oxobicyclo[2.2.1] hept-5-ene-2-carboxylates on hydrolysis.Keywords
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