DEHYDRATION AND ALKYLATION REACTIONS BY THE USE OF PERCHLORATE SALTS
- 5 April 1972
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 1 (4) , 287-290
- https://doi.org/10.1246/cl.1972.287
Abstract
By the treatment of secondary and tertiary benzylic alcohols or tertiary aliphatic alcohols with AgClO4, in benzene at refluxing temperature for 20 to 420 min, olefins were obtained as dehydrated products in good yields. Further, a new procedure for generating tin perchlorate was devised, and the application of this reagent to alkylation reactions of aromatic compounds from alcohols or paraformaldehyde was investigated.Keywords
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- Silver(I)-catalyzed conversion of bicyclobutanes to butadienes. Concerning stereospecificityJournal of the American Chemical Society, 1971
- Dehydration of Alcohols in Dimethyl Sulfoxide1,2The Journal of Organic Chemistry, 1962