Synthesis, structure and reactivity of homo- and hetero-polynuclear complexes of platinum bearing CCR groups as unique bridging ligands
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 13,p. 2587-2599
- https://doi.org/10.1039/dt9960002587
Abstract
Recent advances in the preparation of bi- or poly-nuclear platinum complexes bridged only by alkynyl ligands are described. Emphasis is placed not only on the co-ordination modes of alkynyl ligands but also on their migration and chemical activation.Keywords
This publication has 119 references indexed in Scilit:
- Synthesis and Oxidation of Platinum(II) Ferrocenylacetylide Complexes, trans-[Pt(C.tplbond.CFc)(Ar)(Ph3P)2]Organometallics, 1995
- A Gold(I) [2]CateneAngewandte Chemie International Edition in English, 1995
- Synthesis of .sigma.,.eta.2-Alkynyl-Bridged Bimetallic Complexes Containing ansa-Metallocene and Low-Valent Nickel-Monocarbonyl EntitiesOrganometallics, 1995
- Reactions of Heterodinuclear .mu.-Ethynediyl Palladium-Platinum Complexes with Isocyanides: Living Polymerization of Aryl IsocyanidesOrganometallics, 1994
- Preparation of doubly acetylide-bridged binuclear platinum-platinum and platinum-palladium complexes. Structures of [[(dppe)Pt(C.tplbond.CPh)2]Pt(C6F5)2] and (PMePh3)2[(C6F5)2Pt(.mu.-C.tplbond.CPh)2Pt(C6F5)2]Organometallics, 1992
- Metalation of alkynes. 5. Reaction of diphenylethyne with mercuric salts in alcohols. Synthesis, stereochemistry, and structure of (.beta.-alkoxyvinyl)mercury adductsOrganometallics, 1990
- Mercury(II) trifluoroacetate-mediated transformation of 3-bromo-1-phenylprop-2-ynyl aryl ethers; a novel synthesis of flavanonesJournal of the Chemical Society, Chemical Communications, 1990
- Metalation of alkynes. 4. The methoxymercuration reactionThe Journal of Organic Chemistry, 1989
- Synthesis of organosamarium complexes containing samarium-carbon and samarium-phosphorus bonds. Crystallographic characterization of [(MeC5H4)2SmC.tplbond.CCMe3]2Organometallics, 1983
- Catalysis by Molecular Metal ClustersAngewandte Chemie International Edition in English, 1983