The mechanism of displacement of sulphur from adenosine 5′-[(S)α-thio-γ-benzyl] triphosphate
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 377-378
- https://doi.org/10.1039/c39880000377
Abstract
Adenosine 5′-[(S)α-thio-γ-benzyl]triphosphate on treatment with cyanogen bromide in [18O]water gives [α-18O]- and [γ-18O]-adenosine 5′-[γ-benzyl]triphosphate in about equal amounts, the [α-18O] material being formed with retention of configuration at phosphorus providing support for a mechanism involving participation by the γ-phosphate group.Keywords
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