FACILE LIGAND DISPLACEMENT IN THE COMPLEX CATION BY DIPHOSPHINES BIS (1, IO-PHENANTHROLINE-COPPER(1)
- 1 December 1988
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 18 (4) , 335-337
- https://doi.org/10.1080/00958978808080973
Abstract
Ligand substitution occurs readily at room temperature upon mixing stoichiometric quantities of [Cu(phen)] NO, and free triphenylphosphine or diphosphines Ph, P(CH), PPh, (n = 1–3). The resultant cationic complexes [Cu(phen)(PP)]X are isolated as PF,- or NO,- salts in high yields.Keywords
This publication has 22 references indexed in Scilit:
- The basis of aryl substituent effects on charge-transfer absorption intensitiesInorganic Chemistry, 1986
- Kinetics of oxidation of cuprous complexes of substituted phenanthroline and 2,2'-bipyridyl by molecular oxygen and by hydrogen peroxide in aqueous solutionInorganic Chemistry, 1985
- Autoreduction of copper(II) complexes of 6,6′-diakyl-2,2′-bipyridine and characterization of their copper(I) complexesInorganica Chimica Acta, 1984
- Electron exchange between bis(1,10-phenanthroline)copper(1+) adsorbed on graphite and bis(1,10-phenanthroline)copper(2+) in solutionInorganic Chemistry, 1984
- Secondary structure specificity of the nuclease activity of the 1,10-phenanthroline-copper complex.Proceedings of the National Academy of Sciences, 1984
- Mechanisms of the dismutation of superoxide catalyzed by the copper(II) phenanthroline complex and of the oxidation of the copper(I) phenanthroline complex by oxygen in aqueous solutionJournal of the American Chemical Society, 1983
- Substituent effects and the photoluminescence of Cu(PPh3)2(NN)+ systemsInorganic Chemistry, 1983
- Luminescence of some CuI complexesJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1982
- Photostudies of 2,2'-bipyridine bis(triphenylphosphine)copper(1+), 1,10-phenanthroline bis(triphenylphosphine)copper(1+), and 2,9-dimethyl-1,10-phenanthroline bis(triphenylphosphine)copper(1+) in solution and in rigid, low-temperature glasses. Simultaneous multiple emissions from intraligand and charge-transfer statesJournal of the American Chemical Society, 1981
- Simultaneous emissions including intraligand emission and charge-transfer emission from [bis(triphenylphosphine)(phenanthroline)copper](1+)Journal of the American Chemical Society, 1979