Semiclassical three-dimensional model for vibrational relaxation. II.
- 15 February 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (4) , 1480-1487
- https://doi.org/10.1063/1.430609
Abstract
A three−dimensional semiclassical model for vibrational/rotational transitions has been extended to include an infinite order treatment of the rotational transitions. An analytical expression for the transition probabilities is obtained by using an effective potential and a simple collision trajectory. Numerical results for the Ar−N2 and the I2(B3Π0u+) + He4 systems have been obtained.Keywords
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