Unusual Cationic Single-Bridged Binuclear Complexes of Gold(I) and Gold(III)
- 1 January 1979
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 9 (4) , 317-324
- https://doi.org/10.1080/00945717908069748
Abstract
Reactions of AuXPPh3 (X being a potentially bridging ligand) with Au(OClO3)PPh3 (1:1) or with AgBF4 lead to cationic single-bridged binuclear gold(I) complexes of the [Ph3PAu-X-AuPPh3] A type (A = ClO4 or BF4). The corresponding gold(III) complexes of the [Ph3P(C6F5)2Au-X-Au(C6F5)2PPh3]A type are obtained by similar reactions of Au (A) (C6F5)2PPh3 with AuX(C6F5)2PPh3.Keywords
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