Inorganic Grignard reagents. Preparations and reactions of [bromobis(tetrahydrofuran)magnesio]bis(η-cyclopentadienyl) hydridomolybdenum
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 11,p. 1510-1514
- https://doi.org/10.1039/dt9780001510
Abstract
The compound [Mo(η-C5H5)2H{MgBr(thf)2}] is described. It reacts with CO2, PhCH2Br, C3H5Br, MeI, and MeCOCl to give [Mo(η-C5H5)2(CO)], [Mo(η-C5H5)2(CH2Ph)2], [Mo(η-C3H5)(η-C5H5)2][PF6], [Mo(η-C5H5)2HI], Mo(η-C5H5)2(COMe)H], and [Mo(η-C5H5)2(COMe)2] respectively. Reaction paths for these products are discussed.Keywords
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