Oxidative N-dealkylation of N,N-dimethylbenzylamines by metalloporphyrin-catalysed model systems for cytochrome P450 mono-oxygenases
- 1 January 1985
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 64-65
- https://doi.org/10.1039/c39850000064
Abstract
Iodosylbenzene, catalysed by tetraphenylporphyrinato-iron(III) or-manganese(III) chloride, oxidises tertiary amines by an initial one-electron transfer process whereas with t-butyl hydroperoxide with these catalysts the oxidation is initiated by hydrogen atom abstraction.Keywords
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