Solubilities of the silver halides in propylene carbonate mixtures with bis(trifluoroethyl)sulfite
- 1 July 1977
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 55 (13) , 2499-2503
- https://doi.org/10.1139/v77-343
Abstract
The complex solubilities of AgCl, AgBr, and AgI have been measured in several mixed solvents containing propylene carbonate and bis(trifluoroethyl)sulfite. The results indicate that a large inductive effect destabilizes the solvation of silver ions whereas the halide ions appear to be stabilized by coordination with the sulfinyl sulfur. Several physio-chemical properties of pure bis(trifluoroethyl)sulfite are reported.Keywords
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