Identification and geometry of dimers of phosphine and the hydrogen halides HCl and HBr from their rotational spectra detected by pulsed-nozzle, fourier-transform microwave spectroscopy
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 997-998
- https://doi.org/10.1039/c39820000997
Abstract
The rotational spectra of dimers (PH3,HX) formed by phosphine with the hydrogen halides (X = Cl and Br) have been detected by pulsed-nozzle, Fourier-transform microwave spectroscopy and have been interpreted in favour of a dimer gemetry belonging to the C3v point group, with HX lying along the C3 axis of PH3 and oriented so that it forms a hydrogen bond to the phosphorus atom.Keywords
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