Crystal Structure of CsMnF3
- 15 August 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 37 (4) , 697-699
- https://doi.org/10.1063/1.1733149
Abstract
A single‐crystal x‐ray diffraction study shows that CsMnF3 has the hexagonal BaTiO3‐type structure. The space group is P63/mmc. The unit cell with a=6.213 Å, c=15.074 Å contains six formula units. Each cesium atom has 12 fluorine neighbors at an average distance of 3.13 Å. One third of the manganese atoms occupy the centers of fluorine octahedra that share their corners with other octahedra as in the perovskite structure. The remaining two thirds of the manganese atoms are in distorted fluorine octahedra that each share one face and three corners with other octahedra; these manganese atoms are in pairs 3.00 Å apart. The average Mn–F distance in the octahedra is 2.13 Å.Keywords
This publication has 12 references indexed in Scilit:
- Double Resonance and Nuclear Cooling in an AntiferromagnetPhysical Review Letters, 1961
- Magnetic Properties of KMn. II. Weak FerromagnetismPhysical Review B, 1961
- Perovskite-like fluorides. I. Structures of KMnF3, KFeF3, KNiF3and KZnF3. Crystal field effects in the series and in KCrF3and KCuF3Acta Crystallographica, 1961
- The Crystal Structures of KMnF3, KFeF3, KCoF3, KNiF3 and KCuF3 above and below their Néel TemperaturesJournal of the Physics Society Japan, 1961
- Magnetic Properties of KMn. I. Crystallographic StudiesPhysical Review B, 1961
- Magnetic structures of 3d transition metal double fluorides, KMeF3Acta Crystallographica, 1961
- Magnetic Properties of Potassium Iron Group Fluorides KMF3Journal of the Physics Society Japan, 1960
- The Electron Paramagnetic Resonance of Mn2+ Ions Surrounded by an Octahedron of Fluorine IonsJournal of the Physics Society Japan, 1960
- Artificial FluoriteJournal of the Optical Society of America, 1949
- The crystal structure of hexagonal barium titanateActa Crystallographica, 1948