Substituent-dependent asymmetric synthesis of L-threo- and L-erythro-[2,3-2H2]phenylalanine from chiral (Z)-dehydrophenylalanine

1 January 1996

journal article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 16,p. 1875-1876
https://doi.org/10.1039/cc9960001875

Abstract

A stereo-divergent synthesis of L-threo- and L-erythro-[2,3-²H₂]-phenylalanine by a catalytic deuteriation of (Z)-dehydrophenylalanine included in a chiral diketopiperazine ring is accomplished simply by changing the substituents on the nitrogen atoms in the diketopiperazine ring.

Keywords

ASYMMETRIC SYNTHESIS

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