Study of the Isothermal Bulk Copolymerization of Acrylic and Methacrylic Acid Esters
- 1 May 1983
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 19 (7) , 987-997
- https://doi.org/10.1080/00222338308081079
Abstract
The course and kinetics of the isothermal bulk polymerization of ethyl acrylate, 2-ethylhexyl acrylate, and methyl methacrylate and their copolymerization in different mol ratios were studied by differential scanning calorimetry at 363 K. The initiator used was 2,2′-azoisobutyronitrile. The courses of reaction, the copolymerization enthalpies, the copolymerization parameters, and the specific constants of the rate of polymerization were determined.Keywords
This publication has 13 references indexed in Scilit:
- Influence of zncl2 on the bulk polymerization of methyl acrylate, methyl methacrylate, and methyl‐2‐chloroacrylate studied by differential scanning calorimetryJournal of Polymer Science: Polymer Symposia, 1981
- High conversion polymerization. VI. Detailed examination of the kinetic modelJournal of Polymer Science: Polymer Chemistry Edition, 1980
- High‐conversion polymerization. I. Theory and application to methyl methacrylateJournal of Polymer Science: Polymer Chemistry Edition, 1976
- Study of the free-radical polymerization of styrene by differential scanning calorimetryAnalytical Chemistry, 1973
- The Kinetics of Free Radical Polymerization under Conditions of Diffusion-controlled TerminationJournal of the American Chemical Society, 1962
- Diffusion-controlled termination in free radical copolymerizationTransactions of the Faraday Society, 1962
- A thermocouple method of following the non-stationary state of chemical reactions - III. The evaluation of velocity coefficients and energies of activation for the propagation and termination reactions for the initial and later stages of the polymerization of butyl acrylateProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1959
- Polymerization of esters of methacrylic acid. Part I.—the polymerization of n-butyl methacrylateTransactions of the Faraday Society, 1953
- Rate Constants in Free Radical Polymerizations. IV. Methyl Acrylate1Journal of the American Chemical Society, 1951
- Heat of copolymerizationJournal of Polymer Science, 1949