A new heterobimetallic Zr–Rh complex, [{(η5-C5H5)2ZrCl(CH2PPh2)}2Rh (CO)Cl], leading to an unexpected terminal carbonyl-zirconium bond
- 1 January 1982
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1300-1301
- https://doi.org/10.1039/c39820001300
Abstract
The heterobimetallic complex trans-[{(η5-C5H5)2ZrCl(CH2PPh2)}2Rh(Co)Cl] has beeen prepared and found to react with CO to give unexpectedly the zirconium carbonyl complex [{(η5-C5H5)2Zr(CO)Cl(CH2PPh2)}2Rh-(CO)Cl]; an acyl complex is obtained when the uncomplexed {(η5-C5H5)2ZrCl(CH2PPh2)} reacts with Co.Keywords
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