Chelating and Bridging Modes of Coordination by 1,3-Bis(pyrazol-1-yl)propane; Coexistence of Discrete and Polymeric Metallosupramolecular Isomers within the Same Crystal
- 1 January 2002
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 55 (8) , 519-522
- https://doi.org/10.1071/ch02061
Abstract
1,3-Bis(pyrazol-1-yl)propane (1) reacts with zinc acetate and cadmium nitrate to give tetrahedral [Zn(1)(OAc)2] and eight-coordinate [Cd(1)2(NO3)2] mononuclear complexes (2) and (3), respectively. Reaction with silver nitrate results in the formation of an intriguing complex (4) that consists of discrete M2L2 binuclear units stacked between [ML]n polymeric chains.Keywords
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