Structure Optimization in Colloidal Reinforcing Fillers: Precipitated Silica

Publisher Website
Google Scholar
Abstract
In an attempt to elucidate the role of filler morphology in elastomer reinforcement, we use x-ray, light and neutron scattering to determine the structure of precipitated silica powders. We find the signatures of at least three levels of structure: primary particles, aggregates and agglomerates. By observing the evolution of the scattering profile during solution synthesis, we are able to identify when these structures appear. We also investigate the effect of ionic strength on morphology and find evidence for the interpenetration of aggregates on drying of powders prepared at low ionic strength. Using a reinforcement model by Witten, Rubinstein and Colby, we conclude that the ideal filler will consist of soft agglomerates made up of hard aggregates. Based on the dependence of morphology on synthetic protocol, we present strategies for design of efficient reinforcing fillers.

This publication has 0 references indexed in Scilit: