Thermodynamics of Phase-Change Energy Storage: The Effects of Liquid Superheating During Melting, and Irreversibility During Solidification

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Abstract
This paper considers the question of whether the optimum phase-change temperature for maximum exergy storage is universally equal to the geometric mean of the heat source and environment temperature, Tm=(T∞Te)1/2. The study consists of three parts. The first deals with the conduction-melting process, and shows that the optimum melting temperature is generally greater than the geometric mean of the source and environment temperatures. The second part covers the conduction-solidification process, and concludes that the irreversibility of solidification decreases monotonically as the phase-change temperature increases. The third part treats the complete cycle of melting (storage) followed by solidification (retrieval), and demonstrates that the optimum phase-change temperature is greater than the optimum temperature of the melting process alone.

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