Synthesis of polychloro compounds with aluminium chloride VIII. Decachlorohexadiene‐1,5, its isomerisation, cyclisation and cleavage
- 1 January 1949
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 68 (5) , 419-425
- https://doi.org/10.1002/recl.19490680504
Abstract
The present paper describes the action of dechlorination agents upon hexachloropropene the preparation of decachlorohexadiene‐1,5, of a liquid isomer, probably decachlorohexadiene‐2,4, the cleavage and the cyclisation of both compounds. The compound obtained by cyclisation, a decachloromethylcyclopentene, can be cleaved into carbon tetrachloride and hexachlorocyclopentadiene.Keywords
This publication has 5 references indexed in Scilit:
- Syntheses of polychloro compounds with aluminium chloride VII: The auto‐condensation of 1,2,3,3‐tetrachloropropene‐1Recueil des Travaux Chimiques des Pays-Bas, 1949
- Discussion of the structure of a few polychloro compounds with the help of raman effect dataRecueil des Travaux Chimiques des Pays-Bas, 1947
- Syntheses of polychloro compounds with aluminium chloride. VI: The elimination of hydrogen chloride from polychloro compounds and the formation of cyclic compounds. The synthesis of perchlorocyclopentadieneRecueil des Travaux Chimiques des Pays-Bas, 1946
- The Raman spectra of a number of polychloro compoundsRecueil des Travaux Chimiques des Pays-Bas, 1946
- Vortheilhafte Darstellung von PerchloräthanEuropean Journal of Inorganic Chemistry, 1905