A Direct Synthesis of Vinylic Phosphonates from Vinylic Halides
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 10 (12) , 933-937
- https://doi.org/10.1080/00397918008061854
Abstract
Approaches to the formation of vinylic phosphonates through direct replacement of a vinylic halide by phosphorus have received considerable attention. With the exception of α,β-unsaturated systems1,2 attempts involving simple Michaelis-Arbuzov reaction conditions (heating, trivalent phosphorus ester) have failed.3–5 Other efforts involving transition metal salts as catalysts have found greater, but still quite limited success.6–8Keywords
This publication has 2 references indexed in Scilit:
- Metal salt-catalysed carbenoids. Part IX. The catalysts in trialkyl phosphite–copper(I) complex catalysed decomposition of diazomalonic esters in cycloalkenesJ. Chem. Soc., Dalton Trans., 1975
- Über Carbonyl‐ und Cyan‐phosphonsäure‐ester, III. Ungesättigte Phosphonsäure‐ester aus Hydroxymethylen‐äthernEuropean Journal of Inorganic Chemistry, 1959