The Reaction of Thiazylfluoride with Hexafluoropropene
- 1 January 1978
- journal article
- research article
- Published by Wiley in Israel Journal of Chemistry
- Vol. 17 (1-2) , 137-140
- https://doi.org/10.1002/ijch.197800019
Abstract
NSF (1) reacts with CF3CF=CF2 in the presence of CsF to give the known sulfides (CF3)3CF‐S‐S‐CF(CF3)2 (3) and (CF3)2CF‐S‐CF(CF3)2 (4) and the linear thiazenes (CF3)2C=N‐S‐CF(CF3)2 (5), (CF3)2CF‐S‐N=S=N‐CF(CF3)2 (6), [(CF3)2CF‐S‐N=]2S (7), and (CF3)2CF‐S‐NSF2 (8); (CF3)2CF‐S‐NSO (9) results from the decomposition of (8) with glass. Yields of (3)‐(9) depend on the reaction conditons; an attempt is made to explain the formation of the products.Keywords
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