Ring opening of the benzothiazole system
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 732
- https://doi.org/10.1039/c39740000732
Abstract
6-Nitrobenzothiazole reacts reversibly with methoxide ion at room temperature in Me2SO giving an anionic adduct which with MeI or Br2 and pyridine in CCl4 yields 2-methoxymethylenamino-5-nitrophenyl methyl sulphide and bis-(2-methoxymethyleneamino-5-nitrophenyl) disulphide, respectively.Keywords
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