The effect of radical size and structure on the orientation of addition of perfluoroalkyl radicals to fluoro-alkenes

Abstract
The orientation of the addition of CF3·, C2F5·, n-C3F7·, n-C4F9·, n-C7F15·, n-C7F18·, and (CF3)2CF· radicals to CFHCH2, CF2 CH2, and CFHCF2 has been determined in the gas phase.

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