Elastic Loss and Relaxation Times in Cross-Linked Polymers
- 1 February 1946
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 14 (2) , 51-56
- https://doi.org/10.1063/1.1724105
Abstract
The outlines of a theory of elastic loss in cross‐linked polymers are developed on the basis of the ideas underlying the theory of dielectric loss of Fuoss and the writer and the three‐dimensional network model of rubber structure proposed by James and Guth. The relaxation time distribution function for elastic loss is given in the approximation of free internal rotation of chain segments of the net. The influence of intermolecular hindering torques and network restraints on the relaxation time spectrum is discussed, but explicit calculations are postponed for a later report.Keywords
This publication has 10 references indexed in Scilit:
- A Molecular Theory of the Viscoelastic Behavior of an Amorphous Linear PolymerThe Journal of Chemical Physics, 1944
- Network Structure and the Elastic Properties of Vulcanized Rubber.Chemical Reviews, 1944
- Stress-strain data for vulcanised rubber under various types of deformationTransactions of the Faraday Society, 1944
- Theory of the Elastic Properties of RubberThe Journal of Chemical Physics, 1943
- Statistical Thermodynamics of RubberThe Journal of Chemical Physics, 1942
- Dielectric Relaxation as a Chemical Rate ProcessReviews of Modern Physics, 1942
- Anomalous Dispersion and Dielectric Loss in Polar PolymersThe Journal of Chemical Physics, 1941
- The Viscous Flow of Large MoleculesJournal of the American Chemical Society, 1940
- Beziehungen zwischen Molekülgröße, statistischer Molekülgestalt und elastischen Eigenschaften hochpolymerer StoffeColloid and Polymer Science, 1936
- Zur innermolekularen, Statistik, insbesondere bei Kettenmolekiilen IMonatshefte für Chemie / Chemical Monthly, 1934