Addition of chlorine to the cyanogen bond. Chlorothio(dichloroformimido)cyanamide
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- No. 7,p. 875-878
- https://doi.org/10.1039/j39700000875
Abstract
The reaction of thionyl chloride and salts of dicyanamide, with dimethylformamide as a catalyst, leads to the novel product chlorothio(dichloroformimido) cyanamide(I). Evidence for the structure is presented and the unexpected course of the reaction is discussed. Reactions of this stable, but extremely reactive compound with water, acids, alcohols, ethylene oxide, and amines are described.Keywords
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