Borylated Polythiophene
- 22 June 2007
- journal article
- synthesis of-materials-and-unnatural-products
- Published by Georg Thieme Verlag KG in Synfacts
- Vol. 2007 (7) , 0705
- https://doi.org/10.1055/s-2007-968651
Abstract
In this communication, Li and co-workers reported the synthesis of a borylated polythiophene via a B/Si exchange reaction. The trimethylsilyl- and hexyl-substituted polythiophene 1 was prepared by employing a typical Stille-type polycondensation. This polymer was then treated in sequence with BBr3 and MesCu, leading to novel borylated polymer 2, which was characterized by NMR, MALDI-TOF, and GPC. The authors also examined its conformation, photophysical properties, and electrochemical properties.Keywords
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