Vibrational spectra of methylthiirane
- 1 February 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 86 (3) , 1140-1146
- https://doi.org/10.1063/1.452257
Abstract
Vibrational Raman, infrared absorption, and infrared circular dichroism (VCD) spectra were measured for methylthiirane. Ab inito vibrational frequencies were calculated with a 6‐31G basis, and vibrational assignments were suggested by comparing the experimental and theoretical data. These assignments were used for the interpretation of the experimental VCD spectrum of (R)‐methylthiirane.Keywords
This publication has 19 references indexed in Scilit:
- Vibrational circular dichroism of phenylcarbinols. A configurational correlationJournal of the American Chemical Society, 1986
- Ab initio theoretical frequencies and intensities in the interpretation of infrared spectraJournal of the American Chemical Society, 1984
- A Design of Raman Spectrograph for Optical Activity and Normal Raman MeasurementsApplied Spectroscopy, 1983
- Raman spectra of gases. XVII: Two‐quantum torsional transitions in some methyl‐substituted small ring compoundsJournal of Raman Spectroscopy, 1975
- Optical rotatory properties of synthetic polymers. II. Optical rotatory dispersion of poly(propylene sulfide)Journal of Polymer Science Part A-1: Polymer Chemistry, 1971
- Torsional frequencies in the far infrared—III: The form of the potential curve for hindered internal rotation of a methyl groupSpectrochimica Acta, 1963
- Some Observations on the Reaction of Alkali Thiocyanates with Epoxides1Journal of the American Chemical Society, 1953
- The Configuration of Optically Active 1,2-DichloropropaneJournal of the American Chemical Society, 1951
- The Formation and Ring-Opening of Alkene SulfidesJournal of the American Chemical Society, 1951
- The Synthesis of Amino Mercaptans from Olefin Sulfides1Journal of the American Chemical Society, 1947