Complexes of pyridine-2-thiol with some transition metals

1 January 1974

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.

No. 9,p. 946-951
https://doi.org/10.1039/dt9740000946

Abstract

Pyridine-2-thiol (LH) complexes of iron(II), cobalt(II), nickel(II), copper(II), copper(I), rhodium(II), and palladium-(II) have been prepared and characterised by infrared and electronic spectroscopy and by magnetic susceptibility measurements. With the exception of PdL₂(LH) all the complexes have unidentate pyridine-2-thiol, most of them showing an N–H stretching frequency confirming other evidence that the donor atom is sulphur.

Keywords

PYRIDINE
TRANSITION
PDL2
UNIDENTATE
PALLADIUM
RHODIUM
CHARACTERISED
EXCEPTION
COBALT

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