[PdCl2(PEt3)2]-Catalysed formation of 1,4-disilacyclohexa-2,5-diene from 1-silacyclopropene

Abstract
Photolysis of phenylpentamethyldisilanylacetylene in the presence of [PdCl2(PEt3)2] afforded 1,1,4,4-tetramethyl-2,5-bis(trimethylsilyl)-3,6-diphenyl-1,4-disilacyclohexa-2,5-diene via dimerization of an initially formed 1-silacyclopropene.

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