The first pillared three-dimensional structure constructed by carboxylate ligands bridging heterometallic trilayers
- 19 December 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 105-106
- https://doi.org/10.1039/b007344j
Abstract
Reaction of an aqueous solution of Na2bpdc (H2bpdc = biphenyldicarboxylic acid) with an organic solution of Co(NO3)2via a diffusion route leads to a pillared three-dimensional structure in which the heterometallic sodium(I)–cobalt(II) trilayers are connected by carboxylate groups of the pillared ligand bpdc2−.Keywords
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