Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1543-1545
- https://doi.org/10.1039/c39870001543
Abstract
Sixteen-electron RhI complexes of basic phosphines react with CH2Cl2 yielding either RhCH2Cl or RhCH2PMe3 complexes; an example of each has been structurally characterized.Keywords
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