Synthese und Struktur der dreidimensionalen Koordinationspolymere [(Me3Sn)4M(CN)8] (M Mo, W)
- 17 November 1995
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 107 (22) , 2759-2760
- https://doi.org/10.1002/ange.19951072231
Abstract
Ineinander diffundierende Lösungen der Komponenten K4[Mo(CN)8] und Me3SnCl führen zur Bildung von 1, dem ersten dreidimensionalen, großporigen Polymer, aus dem sich zumindest ein Teil der Lösungsmittelmoleküle entfernen läßt, ohne daß die Struktur zusammenbricht. (Ausschnitt aus der Struktur von 1 rechts). Mit K4[W(CN)8] erhält man ganz analog die entsprechende Wolframverbindung [(Me3Sn)4Mo(CN)8(THF)n] 1. magnified imageKeywords
This publication has 13 references indexed in Scilit:
- [(Me3SnIV)2MoVIO4]: An Organometallic Quasi‐AB2 System with a Layered StructureAngewandte Chemie International Edition in English, 1993
- [(Me3SnIV)2MoVIO4], ein metallorganisches quasi-AB2-System mit SchichtstrukturAngewandte Chemie, 1993
- Supramolecular organolead(IV) and -tin(IV) systems [(Me3EIV)3MIII(CN)6].infin. (E = Pb or Sn, M = Co or Fe): comparative x-ray diffraction and solid-state multinuclear magnetic resonance studiesOrganometallics, 1992
- Novel cage-like cavity accommodating a pair of guest molecules in the structure ofcatena-[dl-1,2-diaminopropanecadmium(II) tetra-?-cyanocadmate(II)]-(1,2-dichloroethane)(1/1)Journal of inclusion phenomena and molecular recognition in chemistry, 1991
- The crystal structures of ?, ?-diaminoalkanecadmium(II) tetracyanonickelate(II)-Aromatic molecule inclusion compounds. V. Toluidine clathrates of the hosts built of the diamines, 1,4-diaminobutane, 1.5-diaminonentane, and 1,8-diaminooctaneJournal of inclusion phenomena and molecular recognition in chemistry, 1991
- The archetype for a new class of simple extended 3D honeycomb frameworks. The synthesis and x-ray crystal structures of Cd(CN)5/3(OH)1/3.1/3(C6H12N4), Cd(CN)2.1/3(C6H12N4), and Cd(Cn)2.2/3H2O.tBuOH (C6H12N4 = hexamethylenetetramine) revealing two topologically equivalent but geometrically different frameworksJournal of the American Chemical Society, 1991
- Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2Journal of the American Chemical Society, 1990
- Bridge Addition Compounds. III. The Influence of Boron-Containing Lewis Acids on Electronic Spectra, Vibrational Spectra, and Oxidation Potentials of Some Iron-Cynanide ComplexesJournal of the American Chemical Society, 1966
- Studies of the Bonding in Acetonitrile Adducts1Journal of the American Chemical Society, 1966
- The Structure of Potassium Molybdocyanide Dihydrate. The Configuration of the Molybdenum Octocyanide GroupJournal of the American Chemical Society, 1939