Hexaarm star-shaped polystyrenes by core-first method
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 2433-2434
- https://doi.org/10.1039/c39940002433
Abstract
The hexafunctional initiator C6[(CH2)2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH4 reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.Keywords
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