Palladium-catalyzed Reaction of Isoprene with Water in Presence of Carbon Dioxide and Base
- 1 February 1983
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 56 (2) , 637-638
- https://doi.org/10.1246/bcsj.56.637
Abstract
Palladium(0)-catalyzed reaction of isoprene with water was enhanced by the presence of carbon dioxide and a base to give dimethyloctadienols. The same catalyst was found to dehydrate the dimethyloctadienols to afford the corresponding dimethyloctatrienes. The effect of acidity of water on the isoprene-water reaction was also studied.Keywords
This publication has 2 references indexed in Scilit:
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- Telomerization reactions of butadiene and CO2 catalyzed by phosphine Pd(0) complexes: (E)-2-ethylidenehept-6-en-5-olide and octadienyl esters of 2-ethylidenehepta-4,6-dienoic acidInorganica Chimica Acta, 1978