Platinum complexes with unsaturated amines. Part IV. The thermodynamics of formation of complexes with some C-substituted allylammonium cations
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 328-330
- https://doi.org/10.1039/j19670000328
Abstract
Stability constants for the formation of platinum(II)–olefin complexes for C-substituted allylammonium cations have been measured by a spectrophotometric method. Enthalpy and entropy changes for this reaction, obtained from the temperature-dependence of the stability constants, indicate that both steric and electronic effects are important in determining the strength of the platinum(II)–olefin bond.Keywords
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