Direct enantioselective synthesis of syn-1,3-diols by the reaction of aldehydes with enol silyl ethers in the presence of a chiral borane complex. Successive asymmetric aldol reaction and asymmetric reduction with one promoter
- 13 June 1994
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 35 (24) , 4107-4110
- https://doi.org/10.1016/s0040-4039(00)73125-x
Abstract
No abstract availableKeywords
This publication has 12 references indexed in Scilit:
- The catalytic asymmetric aldol reaction of silyl ketene acetals with aldehydes in the presence of a chiral borane complex. Nitroethane as a highly effective solvent for catalytic conditionsTetrahedron Letters, 1992
- Enantioselective chiral borane-mediated aldol reactions of silyl ketene acetals with aldehydes. The novel effect of the trialkysilyl group of the silyl ketene acetal on the reaction courseThe Journal of Organic Chemistry, 1991
- Samarium-catalyzed intramolecular Tishchenko reduction of .beta.-hydroxy ketones. A stereoselective approach to the synthesis of differentiated anti 1,3-diol monoestersJournal of the American Chemical Society, 1990
- Reduction of .beta.-hydroxy ketones with catecholborane. A stereoselective approach to the synthesis of syn-1,3-diolsThe Journal of Organic Chemistry, 1990
- Recent progress in 1,3-polyol synthesis.Journal of Synthetic Organic Chemistry, Japan, 1990
- Studies on asymmetric synthesis of β-hydroxy-δ-lactone inhibitors of HMGCoA reductase 1. A new preparation of the lactone moiety of compactinTetrahedron Letters, 1987
- 1,3-syn diastereoselective reduction of β-hydroxyketones with diisobutylaluminum hydride and tributyltin hydrideTetrahedron Letters, 1986
- Synthesis of 2-vinyl-1,3-diols via highly stereoselective reduction of 2-vinyl aldols using trimethylsilyl stereo-directing groupTetrahedron Letters, 1986
- Correlation of configuration and fluorine-19 chemical shifts of .alpha.-methoxy-.alpha.-trifluoromethylphenyl acetate derivativesThe Journal of Organic Chemistry, 1973
- Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) estersJournal of the American Chemical Society, 1973