Polar substituents in pericyclic reactions: photochemistry of 2-cyanobenzobarrelene
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 934-935
- https://doi.org/10.1039/c39740000934
Abstract
Deuterium labelling studies show that 7-cyanobenzocyclo-octene, the major product from the direct irradiation of 2-cyanobenzobarrelene, derives from initial 2π+ 2π bonding between the vinyl and vinylcyano units.Keywords
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