Stereoselective sulfoxidation of α-mannopyranosyl thioglycosides: the exo-anomeric effect in action
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2763-2764
- https://doi.org/10.1039/a804126a
Abstract
As a consequence of the exo-anomeric effect, and in contrast to their β-anomers, α-thioglycosides undergo stereoselective oxidation to give very predominantly the R-sulfoxides, as revealed by X-ray crystallography.Keywords
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