Direct Routes to 5,15-Diaryl-10,20-Diethynyl Porphyrins from Pyrrole

Abstract
5,15-bis(trimethylsilylethynyl)-10,20-diaryl porphyrins can be synthesised from pyrrole in two steps either by reaction of meso-(trimethylsilylethynyl)dipyrromethanes with benzaldehydes or by reaction of meso-aryldipyrromethanes with trimethylsilylpropynal; the latter route is more efficient.

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