X-ray observation of electroclinic layer constriction and rearrangement in a chiral smectic-A liquid crystal

Abstract
An x-ray scattering study of electroclinic layer constriction verifies the interpretation of the electroclinic effect as field-induced molecular tilt. The tilt angles deduced from the layer spacing changes are in close agreement with those from optical measurements. Layer buckling, a consequence of the layer constriction, is also observed and may be the cause of the loss of optical contrast observed in electroclinic devices.

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