Rates of OH radical reactions. III. The reaction OH+C2H4+M at 296 °K
- 15 July 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 67 (2) , 674-679
- https://doi.org/10.1063/1.434871
Abstract
Absolute rate constants for the reaction OH+C2H4+M were determined at 296 °K over a pressure range of various third bodies, M, using the flash‐photolysis resonance absorption technique. The rate constant was found to depend on the pressure and the nature of the third body; H2O, SF6, and CF4 were found to be efficient third bodies, while He was found to be relatively inefficient. The limiting value of kII at high pressure, kII∞, was found to be kII∞=6±1×1012 cm3 mol−1 s−1. This value is recommended for use in modeling of tropospheric processes.Keywords
This publication has 19 references indexed in Scilit:
- Rate constants for the gas–phase reactions of OH radicals with ethylene and halogenated ethylene compoundsThe Journal of Chemical Physics, 1976
- Reaction of hydroxyl radical with ethyleneThe Journal of Physical Chemistry, 1976
- Relative rate constants for reaction of the hydroxyl radical with a series of alkanes, alkenes, and aromatic hydrocarbonsThe Journal of Physical Chemistry, 1976
- Comment on the reaction of OH with C2H4The Journal of Chemical Physics, 1976
- Rates of OH Radical Reactions. I. Reactions with H2, CH4, C2H6, and C3H8 at 295 KCanadian Journal of Chemistry, 1975
- Kinetics of the reaction of hydroxyl radicals with ethylene, propylene, 1-butene, and trans-2-buteneThe Journal of Physical Chemistry, 1975
- Photolysis of Ethylene at 1634 Å and 1849 ÅBulletin of the Chemical Society of Japan, 1973
- Relative Rate of Reaction of O(1D2) with N2OCanadian Journal of Chemistry, 1972
- Competitive Reactions of the Excited Oxygen Atoms, O(1D)*Journal of the American Chemical Society, 1969
- Reaction of O(1D) with hydrocarbons in liquid argonThe Journal of Physical Chemistry, 1969