Preparation and Reaction of 1-(Methylthio- and phenylthio)vinyllithium Reagents
- 1 July 1984
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 57 (7) , 1863-1869
- https://doi.org/10.1246/bcsj.57.1863
Abstract
An improved procedure for the preparation of 1-(methylthio- and phenylthio)vinyllithium reagents utilizing 2-methoxyalkyl sulfides was developed and their reactions with ketones, aldehydes, oxiranes, and alkyl halides were studied.This publication has 12 references indexed in Scilit:
- The Formation of Vinyl Sulfides by the Cleavage of the Carbon-Sulfur Bond in Dithioacetals with CuCl2Bulletin of the Chemical Society of Japan, 1983
- Stereocontrolled preparation of chiral (E)-1-alkenyl sulfoxides. Efficient reduction of alkenyl sulfoxides to the corresponding alkenyl sulfidesThe Journal of Organic Chemistry, 1978
- Acyl anion equivalents: synthesis of ketones and enones from α-phenylthioalkylphosphine oxidesJournal of the Chemical Society, Perkin Transactions 1, 1977
- New synthesis of ketones using 1-(alkylthio)vinyllithiumJournal of the American Chemical Society, 1973
- Vinyl anionJournal of the American Chemical Society, 1972
- New synthesis of .alpha.,.beta.-unsaturated aldehydes using 1,3-bis(methylthio)allyllithiumJournal of the American Chemical Society, 1971
- The Reactions of Phosphonium Ylides and Oxosulfonium Methylide with Sulfenamide DerivativesBulletin of the Chemical Society of Japan, 1970
- Application of lithium reagents from (1-methylthio) alkylphosphonate esters to the synthesis of ketonesThe Journal of Organic Chemistry, 1970
- Phenylthiomethyllithium and Bis(phenylthio)methyllithiumThe Journal of Organic Chemistry, 1966
- Configurational Stabilities of Stereoisomeric Vinyllithium Compounds1aJournal of the American Chemical Society, 1958