New effective synthons for supramolecular self-assembly of meso-carboxyphenylporphyrins
- 20 March 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 585-586
- https://doi.org/10.1039/b001189o
Abstract
Tesselation of new supramolecular motifs of the tetra(4-carboxyphenyl)porphyrin building blocks by metal ion templates has been demonstrated in crystals, characterizing the square-planar [Na+·(–COOH)4·X− ] and the tetrahedral [Zn2+·(–COOH)2·(–COO −)2] molecular recognition elements for effective multiporphyrin assembly.Keywords
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