The N.M.R. spectrum of ethene in a nematic solvent
- 1 January 1969
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 17 (1) , 75-79
- https://doi.org/10.1080/00268976900100801
Abstract
The N.M.R. spectrum of ethene, oriented in the nematic phase of 4,4′-di-n-hexyloxyazoxybenzene, has been measured and interpreted. The absolute signs of the indirect coupling constants and the ratio x = r cis/tr gem have been determined. This ratio is compared with data derived from electron diffraction, infra-red and Raman spectroscopy. The agreement is satisfactory. A discussion is given of vibrational corrections; the importance of anharmonicity is stressed.Keywords
This publication has 15 references indexed in Scilit:
- Chapter 2 High resolution nuclear magnetic resonance in partially oriented moleculesProgress in Nuclear Magnetic Resonance Spectroscopy, 1967
- Molecular Structure of Cyclopropane from Its Proton NMR in a Nematic SolventThe Journal of Chemical Physics, 1967
- Vibrational—Rotational Study of the Electronic Ground State of the Hydrogen MoleculeThe Journal of Chemical Physics, 1966
- Analysis of Nuclear Magnetic Resonance Spectra of Molecules in Liquid-Crystal SolventsThe Journal of Chemical Physics, 1965
- Electron-Diffraction Study of the Structures of C2H4 and C2D4The Journal of Chemical Physics, 1965
- High-Resolution Nuclear Magnetic Resonance Spectra of Orientated MoleculesPhysical Review Letters, 1963
- High-Resolutjon nuclear-magnetic-resonance spectra of hydrocarbon groupings VI. The hydrogen spectra of carbon-13 substituted ethane, ethylene and acetyleneProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1962
- The Structure of Ethylene from Infrared Spectra1Journal of the American Chemical Society, 1958
- The Influence of Anharmonicity upon the Vibrational Probability Density and Mean Amplitudes in Diatomic Molecules.Acta Chemica Scandinavica, 1958
- Effects of Anharmonicity of Vibration on the Diffraction of Electrons by Free MoleculesThe Journal of Chemical Physics, 1955