Divinyltin bistrifluoroacetate and its reactions with sodium salts of metal-carbonyl anions
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1306-1309
- https://doi.org/10.1039/dt9740001306
Abstract
The compound [(CH2 CH)2Sn(O2CCF3)2], (I), has been prepared and characterised by elemental analysis, and 1H, 19F, i.r., and mass spectra. Salt-elimination reactions of compound (I) with Na[Mn(CO)5], Na2[Fe(CO)4], and Na[Co(CO)4] afford [(CH2 CH)2Sn(O2CCF3)2{Mn(CO)5}], (II), [(CH2 CH)2Sn{Mn(CO)5}2], (III), [{(CH2 CH)2Sn[Fe(CO)4]}2], (IV), and [(CH2 CH)2Sn{Co(CO)4}2], (V).Keywords
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