Nuclear spin relaxation and quasicoherent fluctuations in ordered fluids: A different expression for the high-frequency cutoff
- 15 April 1988
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 88 (8) , 4655-4659
- https://doi.org/10.1063/1.453778
Abstract
An expression for the contribution to nuclear spin relaxation rates in liquid crystals from fluctuations in the nematic order has been rederived using an ellipsoidal integration volume for the director modes. When the anisotropic elastic constants, viscosities, and cutoff wavelengths are replaced by effective, isotropic values this expression reduces to the familiar ‘‘one-constant’’ formula, a result which cannot be recovered from expressions based on a cylindrical integration volume. The frequency dependence of the spectral density of motion in various limits as well as practical applications to studies of nematic phases is discussed.Keywords
This publication has 28 references indexed in Scilit:
- On cooperative modes of reorientation in liquid crystalsThe Journal of Chemical Physics, 1983
- Stochastic-molecular theory of spin–relaxation for liquid crystalsThe Journal of Chemical Physics, 1977
- A continuum theory of disorder in nematic liquid crystals. III. Nuclear magnetic relaxationProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1977
- NMR Investigation of Order Fluctuations, Self-Diffusion and Rotational Motions in the Nematic Liquid Crystal MBBA by T1-Relaxation SpectroscopyZeitschrift für Naturforschung A, 1977
- Theory for spin-lattice relaxation in nematic liquid crystalsPhysical Review A, 1976
- Nuclear Spin-Lattice Relaxation in Liquid Crystals by Fluctuations in the Nematic DirectorPhysical Review Letters, 1974
- Proton Spin Relaxation Study of the Dipolar Spin System in Nematic Liquid CrystalsMolecular Crystals and Liquid Crystals, 1974
- Frequency dependence of the proton spin relaxation of the dipolar energy in a liquid crystalThe Journal of Chemical Physics, 1973
- Spin-lattice relaxation in the nematic liquid crystalline phaseChemical Physics Letters, 1970
- Nuclear relaxation in a nematic liquid crystalSolid State Communications, 1969