Kinetics of formation of ethylene oxide hydrate. Part I. Experimental method and congruent solutions
Open Access
- 15 December 1968
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 46 (24) , 3857-3865
- https://doi.org/10.1139/v68-639
Abstract
A dilatometer was constructed for studying the formation of ethylene oxide hydrate. In unstirred, congruent solutions heat transfer appeared to be the significant rate-controlling factor. Initial hydrate formation rates were independent of stirring at speeds greater than approximately 100 r.p.m. Magnetic stirring was inadequate due to hydrate build-up on the walls of the dilatometer bulb. Mechanical stirring eliminated this build-up and gave satisfactory results.Keywords
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