ORGANIC METALS: ELECTROCRYSTALLIZATION OF THE COMPLEXES OF NAPHTHACENO[5,6-cd:11,12-c′d′]BIS[1,2]DITHIOLE AND THEIR ELECTRICAL CONDUCTIVITIES
- 5 May 1982
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 11 (5) , 727-730
- https://doi.org/10.1246/cl.1982.727
Abstract
The complexes of naphthaceno[5,6-cd:11,12-c′d′]bis[1,2]dithiole with inorganic anions (Cl−, Br−, I−, Clo4−, BF4−, PF6−, and SbF6−) were obtained as crystals by an electrochemical technique. The temperature dependences of their electrical conductivities were measured. The PF6 complexes showed 762 (Ω cm)−1 at room temperature, and it was metallic above 220 K.Keywords
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