Optical properties of Pb2+-based aggregated phases in CsBr Thin film and single crystal matrices
- 1 November 1999
- journal article
- research article
- Published by Taylor & Francis in Radiation Effects and Defects in Solids
- Vol. 150 (1-4) , 341-345
- https://doi.org/10.1080/10420159908226254
Abstract
Emission characteristics of CsPbBr3 and Cs4PbBr6 aggregates in CsBr bulk and thin film matrices are reported. The emission of the former aggregated phase is peaking about 520–560 nm. It shows small Stokes shift (50 meV) related to narrow free exciton emission line of sub-nanosecond decay times. Quantum size effect was evidenced for the aggregates of 6–7 nm in diameter. The Cs4PbBr6 aggregates show emission peak at 375 nm and overall emission characteristics are similar to those of KBr: Pb, which is explained by very close local arrangement of emission centres—(PbBr6)4- octahedra—in both structures.Keywords
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